Processing Chemicals
DIAGNOSTIC RADIOGRAPHY · NTA LEVEL 4 · SEMESTER ONE Processing Chemicals CRT04105 · Radiographic Imaging Sciences START READING NOTES Study Processing Chemicals using the sections below. Use the topic navigation to continue through Radiographic Imaging Sciences. Contents of This Topic PROCESSING CHEMICALS LATENT IMAGE LATENT IMAGE CONT. LATENT IMAGE FORMATION LATENT IMAGE FORMATION cont. Its primary purpose is convert latent image into visible image CHEMICAL ACTION OF DEVELOPER Chemical Action of Developer cont.. EFFECTS OF THE BY-PRODUCTS OF DEVELOPMENT CONSTITUTION OF DEVELOPER SOLUTION CONSTITUENTS OF DEVELOPER REPLENISHER SOLUTION SOLVENT – WATER DEVELOPING AGENTS DEVELOPING AGENTS Cont .. ADVANTAGES OF PQ DEVELOPER Advantages of PQ Developer cont… The shape of the characteristic curve is controlled by the two developing agents developer…. ACCELERATORS developer…. Accelerators cont… developer…. BUFFERS developer…. RESTRAINERS PRESERVATIVES SEQUESTERING AGENTS STARTER SOLUTION EFFICIENCY OF DEVELOPMENT & FACTORS AFFECTING DEVELOPMENT HOW CONSTITUTION OF THE DEVELOPER AFFECT DEVELOPMENT? HOW DOES DEVELOPER TEMPERATURE AFFECT DEVELOPMENT? EFFECT OF INCREASE OF TEMPERATURE EFFECT OF DECREASE OF TEMPERATURE DEVELOPER TEMPERATURE IN MANUAL PROCESSING DEVELOPMENT TIME DEVELOPMENT TIME IS DETERMINED BY: Development is the most important part of processing KEY POINTS FIXING (FIXATION) Fixing (fixation), cont… CONSTITUENTS OF FIXING SOLUTION Constituents of Fixing Solution cont… Constituents of Fixing Solution, Chemical reaction cont… Constituents of Fixing Solution cont…ACID Constituents of Fixing Solution cont…HARDENER Constituents of Fixing Solution, Hardener cont… Constituents of Fixing Solution, BUFFER Constituents of Fixing Solution, PRESERVATIVE Constituents of Fixing Solution, ANTI-SLUDGING AGENT Fixing, cont… FACTORS AFFECTING FIXATION Fixing, cont… FACTORS INFLUENCING QUANTITY & QUALITY OF FIXING Fixing…Factors Influencing Quantity & Quality of Fixing: 1.FIXER CONSTITUTION Fixing… Factors Influencing Quantity & Quality of Fixing…1.Constitution cont… Fixing… Factors Influencing Quantity & Quality of Fixing…2. FIXER TEMPERATURE Fixing… Factors Influencing Quantity & Quality of Fixing…3. FIXING TIME Fixing… Factors Influencing Quantity & Quality of Fixing…3. Fixing Time cont… Fixing… Factors Influencing Quantity & Quality of Fixing…3. Fixing Time , Determining Factors cont… Fixing… MAINTENANCE OF FIXER VOLUME Fixing… FACTORS AFFECTING FIXER REPLENISHMENT RATE RINSING, WASHING & DRYING RINSING, WASHING & DRYING: 1. RINSING Rinsing, Washing & Drying: Rinsing cont… Rinsing, Washing & Drying: 2. WASHING Rinsing, Washing & Drying: 2. Washing: FACTORS AFFECTING WASHING EFFICIENCY Rinsing, Washing & Drying: 3. DRYING Rinsing, Washing & Drying: 3. Drying, cont… Rinsing, Washing & Drying: 3. Drying, FACTORS ON DRYING TIME Rinsing, Washing & Drying: 3. Drying… Factors on Drying Time cont… PROCESSING STAGES MANUAL FILM PROCESSING Manual Film Processing, cont…. Manual Film Processing…THE CYCLE Manual Film Processing…The Cycle cont… Manual Film Processing…STOP BATH/RINSING Manual Film Processing…Rinsing/Stop Bath, cont… Manual Film Processing…REPLENISHMENT PROCESSING CHEMICALS PROCESSING CHEMICALS The primary purpose of a radiographic processing is to deposit enough black metallic silver at the latent image sites to permit a permanent visible image to form The development of latent image can be accomplished manually or with automatic processing equipment.The development and fixing are accomplished in a solution of numerous chemicals LATENT IMAGE The silver bromide crystals consist of positive silver and negative ions arranged in geometrical pattern known as a crystal lattice When silver bromide grain is exposed to light or x-ray some of the bromide ions in the lattice emit electrons Electrons are trapped in the electron- trap in the crystal An electron trap is a region of low energy called a sensitivity speck producing during manufacture Electrons tend to collect at sensitivity speck and they confer on speck a negative charge A crystal lattice LATENT IMAGE CONT. Silver ions in the crystal have a positive charge, the silver which are free to move are attracted to the negative charge electrons in a sensitivity speck The negative charge on the electrons neutralises the positive charge on the silver ions; hence forming silver atoms LATENT IMAGE FORMATION How the film works Latent: Hidden – as the silver halide crystals are exposed to electromagnetic radiation, they are ionized and conversion to metallic silver is begun. This is completed in the processor LATENT IMAGE CONT. HOW THE FILM WORKS CONT. Sensitization speck Impurities/imperfections intentionally introduced to crystals during manufacturing. Found on surface of crystal Acts as electron trap, trapping electrons released during ionization of crystals. Essential for development of black metallic silver LATENT IMAGE FORMATION The latent image is theorized as being formed in the following manner: Radiant energy (x-ray photon or light photon from screen) strike the crystal & liberates an electron from the valence shell of a bromide ion. This electron is then free to move about in the crystal. If it strikes a sensitivity speck, it may be trapped giving the speck a negative charge. When a positive silver ion comes within the negative field of the speck, it may be attracted to the speck & take on an electron thus forming an atom of metallic silver LATENT IMAGE FORMATION cont. Occurs many times within the same crystal when struck by radiant energy. Once the film has been exposed to radiant energy & a latent image has been formed, the film is capable of developing a radiographic image. Chemicals in the processor greatly enhance this chemical reaction converting a latent image to a visible image LATENT IMAGE FORMATION cont. IN SUMMARY Electrons (released by light from bromine ions) are trapped Positive silver ions are trapped at the sensitivity speck by the negative charges on the electrons Positive charges on the silver ions are neutralized by negative charges on the electrons and silver atoms form Processing Chemicals Film Processing is a predetermined sequence of chemical treatment of the exposed film whereby the latent image is transformed into a visible image in a dry film. CHEMICALS IN AUTOMATIC PROCESSOR Four stages in Automatic processing namely Development, Fixing, Washing and Drying Developing:- it is the first step in processing film, at this stage silver is deposited at the latent image site and an image becomes visible. Processing Chemicals The deposition of silver amplifies the density of the image, a modern x-ray developers are capable of amplifying the image by a factor of 108 to 10 9 within 3-4 mins . Its primary purpose