Chemistry Form One Notes – Air, Combustion, Rusting and Fire Fighting

Chemistry Form One Notes – Air, Combustion, Rusting and Fire Fighting

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10. Layer separation technique is applied inthe recovery of liquids from contaminants
11. Solvent extraction process is applied in the extraction of certain edible ols from seeds, and in
the extraction of some metals from sludge mixture

AIR COMBUSTION, RUSTING AND FIRE

FIGHTING

101
Composition of air
Air is a mixture of different gases. The gases that make up the air include nitrogen, oxygen,
carbon dioxide, noble gases (argon, helium, neon, krypton and xenon) and a litle water vapour.
‘Air may also contain traces of impurities such a carbon monoxide (CO), sulphur dioxide (SO),
hydrogen sulphide (H;S) and other gases. The presence of these gases in air results in air
pollution. Table bellow shows the composition of air by volume. The proportion of wate vapour
‘The Gases Present in Air and their Proportions
The composition of air isnot exactly the same everywhere. It changes slightly from day to day
and from place to place. There is more water vapour inthe air on a damp day and in air above
‘more carbon dioxide. But the uneven heating of the earth’s surface bythe sun causes the arto
‘move continually, resulting in winds, The resultant winds spread the pollutants around
The percentage composition of air by volume
Gn Approximate percentage
Nawgen rar
Owes 21.00%
Noble ese ais agoa 090%
Carbon donde 003%
Water apour 09%
The Presence of Different Gases in Air
The determination ofr by mass was carted out by Dumas in 1841. The apparatus wed consists
of three units as shown bellow
2
|
E j heating furnace
aes (
potassium ‘concentrated J
gases. If we neglect the weight of carbon dioxide, the percentage of oxygen by mass (weight) in
dry, pure air is 23.2% and the remaining 76.8% is the percentage of nitrogen and rare gases.
‘The presence of nitrogen in air
by strongly heating magnesium inthe residual gas from the above experiment. Magnesium and
nitrogen will react thus:
Upon treatment with water, magnesium nitrite gives ammonia gas, The gas can be recognized by
its characteristic smell and its action of turning red litmus paper to blue.
3M gay + Noe)? MEN
The presence of oxygen in air
Oxygen is known as the ative portion of the air because it supports combustion and combines
with many other substances. Is presence and composition in air can be determined by using
these properties. Any of the following two (2) experiments ean be used to determine the
composition, by volume of oxygen contained in it
‘The Percentage of Oxygen in Air Experimentally
Determine the percentage of oxygen in ar experimentally
1. Experiment, Determination of the presence and proportion of oxygen in air by
combustion of a candle
Method
1. Placea smal candle on aplastic lid or any object that can float, Then setup the apparatus
produced by a burning candle
of cooling is to let the heated and expanded air to return to its normal condition. Then note the
108
meaning cinder ——F \
baring cai
|| etme of arate
4
1 F— oun
b i
Determining the presence and percentage composition of oxygen in air by burning a candle
Observation and findings
The oxygen in air enclosed in the measuring eylinder is used to burn the candle to produce
carbon dioxide gas, The carbon dioxide so produced dissolves in sodium hydroxide solution. The
dissolved carbon dioxide causes the level of sodium hydroxide solution to rise up. The oxygen
21s used to burn the candle is practically equal tothe amount of carbon dioxide produced. This
faci, therefore, used o calculate the percentage of oxygen in ai
Model results
In the experiment, the inital volume ofr was found 1 be 705 em and the inal volume was 55
cm The percentage of oxygen in thea is calculated in two steps:
1. To find the volume of oxygen used up to burn the candle (which is practically equal tothe
volume of carbon dioxide produced and then absorbed by sodium hydroxide), we subtract the
final volume of ar fom the inital volume
Therefore, the volume of oxygen used for combustion ofthe candle = 14.7 em
=705 emi?) -5.0em>
=1470m?
Alteratively, the volume of oxygen used up canbe calculated by subtracting the inital volume
of sodium hydroxide solution fom the final volume, That is: Volume of oxygen used = final
10s
volume of sodium hydroxide ~ inital volume of sodium hydroxide = Volume of carbon dioxide
dissolved in sodium hydroxide.
2. The percentage composition of oxygen in the air=
[Volume of expen vse
Tata volume
= 87.100
705
= 208%
Therefore, the percentage of oxygen =
In practice, it is difficult to get an accurate result withthe above experiment.
Nolume of carbon dioxide dissolved in sodium hydroxide «100
Initial volume of calcium hydroxide
This is due to a number of reasons such as
1. Notall the carbon dioxide is absorbed by the sodium hydroxide
2. The candle may go out (stop burning) before all the oxygen is used up due to
accumulation of carbon dioxide in the cylinder.
3. The heating of the air inside the measuring cylinder causes the gases to expand. This is
‘why it is essential thatthe gases be allowed to cool to room temperature before reading the level
Experiment withcombustion of copper in airgives the more accurate results than the
combustion of the candle. The copper reacts with oxygen in the ar to give copper (ID) oxide.
2. Experiment. Determination of the presence and proportion of oxygen in air by the
combustion of copper in air
Method
1. Setup the apparatus as shown in figure bellow. Syringe A should contain 100 em of ar,
syringe B should be empty
108
‘=f ce <I
~ ‘rubber tubing
‘1. ‘The oxygen in the air reacts with copper to form copper(II)
teoumns
‘Volume after third heating and cooling = 79
The volume of oxygen used up = Initial volume of ir before cooling – volume of air aftr the last
heating and cooling,
= 100-79
=21
‘The presence of earbon dioxide in air
21
The percentage of oxygen in air = 21x 100
=21%
Carbon dioxide is present in air tothe extent of 0.03% by volume. The gas is formed during the
combustion ofall common fuels — wood, coal, coke, natural gas, petrol, diesel, paraffin oil, te,
all of which contain carbon,
Its breathed out as a waste product of respiration by all animals, All sorts of combustion and
bbuming produce carbon dioxide. The gas produced by all these processes accumulates in air
However, the amount of carbon dioxide in air remains constant instead of the tremendous
«quantities released into the atmosphere, This is because plants take up carbon dioxide. They then
convert it into complex starchy compounds during photosynthesis. The gas also dissolves in
‘ocean water and other water bodies.
Cut Oy +0025)
The presence of carbon dioxide in air can be shown by passing air through a test tube containing
some limewater (figure 6.5). After a time, the limewater turns milky. This shows the presence of
carbon dioxide
Te reaction involved is as follows:
108
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Site ee ac
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ree
esa il Thess gdb olin ay bpd
snc haut sats ton inaticusitntencnccrme tech
wonatuecnue
reer ge
o
About 1% of the air by volume is made up of the noble gases. The most abundant of the noble
‘gases is argon. Others are neon, xenon, krypton and helium, The proportion of these four is very
‘minute, Argon and ncon are used in “gas-filled” electric light bulbs and coloured “neon”
clectrical signs. They are obtained ftom liquefied air
Air pollutants
‘The air always contains small quantities of many gases. Such gases include hydrogen sulphide,
sulphur dioxide, as well as dust and other solid particles, especially in industrial areas. These
‘gases are given off during the combustion of coal, and the fuels resulting from coal

SEPARATION OF AIR INTO ITS CONSTITUENT GASES

The air we breathe is necessary to keep us alive. It is also a chemical resource. Oxygen is used in
steel making, and nitrogen is used in making fertilizers. To use these gases in this way, they must
be separated from the atmospheric air. Air, as we studied in chapter 5, is a mixture of different
gases. The method used to separate its constituent gases is fractional distillation. The gases have
tobe liquefied so thatthe mixture can be fractionally distilled.
The process of separating the air into its constituent gases is difficult. It cannot be done in the
laboratory. Ii only done in industry. The chemical industry needs the gases from the ar in their
pure form.
‘The fractional distillation of air involves essentially two stages:
1, Fist, the air must be cooled until it tums int aliquid
2. Then, the liquid air is allowed to warm up again, The various gases bol off at different
temperatures
Stage 1: Liquefaction of air
0
compressed warm op ba 18S
on 4 = fractional
sats aiee
« B) Sb | tae
af CTS ese
Dawa J =
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renner |
See, oom) PLL ee
arse ttt iL, Nat
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—— = |] oie
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Combustion
‘The Concept of Combustion
chemilly with the bring sane to produce anew sbsance, ot we thal ee
m
Combustion of a substance involves its reaction with oxygen and the release of energy. These
reactions are exothermic and often produce a flame. An exothermic reaction isthe one that is
accompanied by release of heat tothe surrounding environment. Combustion in which a flame is
produced is described as burning. During burning energy is given out in the form of heat, light
and sound,
‘The Combustion of Different Substances in Air and Analyse the Products
Demonstrate the combustion of different substances in air and analyse the products
Many diferent substances bum in air to produce different products. Here are examples of
‘combustion of some common substances:
Sulphur
This is a yellow powder. When burnt in ar, it gives misty fumes of sulphur dioxide gas.
‘Sulphur powder + air (oxygen) + sulphur dioxide gas
S(s) + Og) + SOXa)
Copper
‘When a piece of copper foil in pair of tongs is held in a Bunsen flame, it becomes red-hot. On
cooling, a black layer of some substance is observed. This black substance is copper oxide. The
reaction occurs thus:
1
Cooper + air (axygen) = Copper axide
2Culs) + Og) F2Cu0Ks)
Magnesium
‘When one end ofa piece of magnesium ribbon in tongs is placed in a Bunsen flame, it burs with
1 dazzling flame leaving a white ash. This white ash is magnesium oxide,
Mg{s) + 04g) + 2Mgo(s}
3
Hydrocarbons
Candle wax is @ hydrocarbon. When it bums in air, the carbon and hydrogen ofthe wax react
with the oxygen of the arto give carbon dioxide and water vapour respectively

Cs)+ 048) -+ COW)

2H.(g)+ 0.68) + 2H.0@)
‘These are substances containing carbon and hydrogen only. The burning of these organic
substances produces carbon dioxide and water vapour a the main products. If oxygen supply is
low, combustion is incomplete and carbon monoxide may be formed,
Coat
Coal is a slid fue that will urn in ar to give the following products:
Coal + ash + soot smoke + gases (carbon dioxide and
‘The Application of Combustion in Real Life
Describe the application of combustion in real life
1. The combustion of a natural gas isan important source of energy for homes and industry
Natural gas is mainly methane. is complete combustion produces carbon dioxide and water
vapour
CHAg)+ 048) + CO(g)+H.0(@)
Substances like methane, which undergo combustion readily and give out large amount of
2. There are some reactions where fuels and other substances bur to produce aflame. These are
evident. The most important of these isthe crucial biochemical reaction that releases energy in
cour body cells called cellular respiration.
a6
Our bodies need eneray 19 make possible the reactions that take place in our cells. These
reactions allow us to carty out our everyday activities. We need energy to stay alive, We get this
nergy from food. During digestion, food is broken down into simpler substances. For example,
the carbohydrates in ree, potatoes and bread are broken down to form glucose. The combustion
of glucose with oxygen inthe cells of our body provides energy.

Glucose + oxygen => carbon dioxide + water + energy

C.H,.04aq) +6048) + COs) + 084,00)
The reaction is exothermic nd is known as cellular respiration.
3. We combust fuels to heat homes and keep ourselves warm, cook our food, and even burn
4. Combustion of fuels in automobile engines produces power (energy). This energy is supplied
to different parts of motor vehicles to make them move from one point to another oF carry out
some crucial activities such as grinding, pumping, hauling ete. The operation of such machines
could be impossible without combustion of fuel that produces energy to make them work
‘5. Combustion of ful in different bumers produces heat and light used for different purposes in
a chemistry laboratory
6. Extraction of metals: Moderately reactive metals such as zinc, iron and lead are roasted in a
special furnace (kiln) to form oxides. The resulting oxides are then reduced with carbon to get
the pure metal. This process of extracting a metal fom its ore by heating is called smelting
7. In metallurgical industry, combustion is used during welding, Welding is the process of
joining metas by melting the parts and then using a filler to form a joint It can be done using
diferent encrgy sources, including gas lame,
Fire fighting
Firefighting isthe act of extinguishing destructive fires. A fire fighter fight these fires to prevent
destruction of life, property and the environment. Firefighting is highly technical profession
that requires traning and education in order to become proficient.
us
Types of Fires According to their Causes
Classify types of fires according to their causes
Before starting to fight the fire itis important to know the size and type ofthe fire that you are
ning to put off. The kind of firefighting material you are going to use will also depend on the
‘ype ffir in question. Fires are classified based onthe type of burning materials.
1. Class A fires
These are the fires in which the burning materials are ordinary combustible materials such as
paper, wood, cardboard, coal, rubber, clothing, fumiture and most plastics. Water isthe best
extinguisher fr these fires. However, any other type of extinguisher, except carbon dioxide, may
be used
2. Class B fires
These fires involve ammable liquids such as peo, kerosene, oil alcohol, the, vanishes, et.
Fo small fires fire blanket or sand may be use. Ifthe fire is large, use foam, dry powder or
carbon dioxide extinguisher. Water should not be used on clas B fires because the burning
smatra, being lighter than water, will just lot and spread the fire fuer.
3. Class C fires
The burning material involves flammable gases e.g. hydrogen, acetylene, coal ga, butane,
aethane, propane, etc. The best extinguishers to use in Fighing against these fires are foam, dry
powder or carbon dioxide extinguishers. It is important to tum off the gas supply, and spray
water on the gas tank to cool it down
4. Class D fires
‘The burning material sa metal. Alkali metals such as sodium or potassium may catch fie when
they come in contact with water and oxygen. At high temperatures, many metals react with
cnygen vigorously. Fites that involve burning meals should not be extinguished by water, This
is because the burning metal can react with water to give hydrogen (another potential ful). The
appropriate extinguisher to use is foam or dry powder extinguisher
us
5. Class E fires
‘These fires involve electrical equipment such as appliances, wiring, circuit breakers and outlets
‘You may use carbon dioxide or dry powder extinguisher to put off these fires. Never use water as
itcan conduct electricity and give an electric shock, Also remember to switch off power from the
6. Class F fires
The burning material is cooking ol o fat. A cooking oil fre i the kitchen can be extinguished
by covering the pan with a fire blanket or damp cloth. Foam, dry powder or carbon dioxide
extinguishers also work by cutting off the air supply to the fire. For large fires, wet chemical
extinguishers are recommended.
Different Types of Fire Extinguishers used to Extinguish Different Types of
Fire
“deni diferent types of fre extinguishers used extinguish diferent pes offre
Before choosing the best fire extinguishers for fighting different types of fires itis crucial to
‘entity the typeof buing materials rst, and hence the ype of fire such as
(Class A: Solids such as paper, wood, clothing, rubber, ste
Class B: Flammable liquid suchas parafin, petro, ol spirit, alcohol, te.
(Class C: Flammable gases such as propane, butane, methane, hydrogen, et
(Class D: Metals such a aluminium, magnesium, titanium, ete
(Class E: Fires involving electrical equipment such as appliances, circuit breakers and outlets,
‘Types of fire extinguisher to use for each type of fire
Water extinguisher
aw
This isthe cheapest and most widely used fire extinguisher. Iti used for class A fires. I is not
suitable for class B (liquid) fires, or where electricity is involved
Foam extinguisher
This is more expensive than water extinguisher, but more versatile. It is used for classes A and B
fires, Foam spray extinguishers are not recommended for fires involving electricity, but are safer
than water if mistakenly sprayed onto live electrical apparatus.
Dry powder extinguisher
This is often termed as “multi-purpose” extinguisher, as it can be used on classes A, B and C
fies, It isthe best for liquid fires (class B). It will also efficiently extinguish class C (gas) fires.
However, take eare because it ean be dangerous to extinguish a gas fire without first isolating the
‘2 supply. Special powders are available for clas D fires.
‘When powder-type extinguishers are used indoors, the powder can obscure vision or damage
‘goods and machinery. Its also very messy
Carbon dioxide extinguisher
Carbon dioxide is ideal for fires involving electrical apparatus (class E), It will also extinguish
class B (liquid) fires. However, the extinguisher has no post-fire security and the fire could re-
ignite
‘Wet chemical extinguisher
‘This is a special extinguisher for class F fires. The extinguisher contains potassium salts, The
salts not only help to cool down the flames but also form a ‘saponification’ blanket that
effectively smothers the flames with thick, soapy foam,
Specialist ponder extinguisher
This isa specialist fie extinguisher for use on class D fires (fires on combustible metals such as
sodium, potassium, magnesium, lithium, titanium, manganese and aluminium), especially in the
form of powder or turnings,
ue
‘The Components Needed to Start a Fire
Stare the components needed to start a fire
To extinguish fre, it i ocesary to remove one of more ofthe three components of combustion.
Any fire nossa fuel, oxygen (ait) and heat to kesp it going, Remove any one of them and the
fre will go ou. These components are as shown inthe fre triangle below
omen WA \ sen
ZN
// Sito
The fire rangle
‘fire will contin or start to bur i these component are present
(0) Fac: This refers o ny combustible material be it sold, guid oF gaseous material provided
itcan catch fire and burn. You can stop fre by removing the combustible materia rom the path
of re
(i) Oxygen (ar): Onyzen supports combustion. A fuel will only burn if there is sufcient
supply of oxygen. You can extinguish Fire by displacing or taking away oxygen supply from the
fre or by blocking the s33 supply to the fire
(i) Heat: The temperature shouldbe atthe kindling pont of that fel or above it Every Fel has
its own kindling point Below the kindling point, the fue wll not catch fire. You can put out fe
ty lowering the temperature below the kindling point ofa particular ful, Water may be wsed to
cooldown the fel. The vaporization of wate absorbs the hati cools the smoke, at, wall
objects etc, which could be used as further fel
19
Fire Extinguishers According to the Chemicals they Contain
Cassi fire extinguishers according tothe chemicals they contain
Fire extinguishers are classified according tothe typeof chemicals they contain
1. Liquid carbon dioxide extinguisher
This extinguisher contains liquid carbon dioxide. The liquid is contained in a metal container.
‘When the safety pin is removed, carbon dioxide evaporates as solid “snow (carbon dioxide
sublimes). The snow settles onthe fire and suffocates it
2. Soda-acid extinguisher
This extinguisher has a metal case containing soda (aqueous sodium carbonate or sodium
hhydrogen carbonate). In the metal case there is a glass botle containing a concentrated acid
(sulphuric or hydrochloric acid), Ther is a knob attached tothe top of a metal case. Hitting this
nob breaks the acid bottle thus bringing the acid and the soda into contact. The two react to give
carbon dioxide, eg
NaHCO,u)#HCIa) + COsy)+NECl ay + HO 0
The gas forms bubbles withthe solution, thereby forming foam which is forced out ofa et ofthe
case. The foam is directed to the fre where it covers the buring liquid, excloding all ai fom
Some extinguishers are made in such a way that turning them upside down brings the soda and
acid into contact andthe reaction proceeds as stated above
120
Chemical composition of
Type agent ‘Suitable for Unsuitable for
say ks say kn
H smc gnwe 1 LL tee neppee
| |
wa LL gs bane wa
wa = =
“i 3
lca
(@) strike the knob (b) tum upside down
3. Foam extinguishers
This is diferent from the soda-acid type in that it contains sodium hydrogen carbonate inthe
tal case, bu instead ofthe concentrated ac, it contains aluminium sulphate and saponium in
the glass bottle. On mixing the tree components, carbon dioxide gas is produced. The gas is
ejected out as foam, The foam here lass longer than the foam in the soda-acid extinguisher. The
foam so produced also keeps air away from the burning materi
4. Dry chemical extinguisher
This extinguisher uses powdered sodium hydrogen carbonate and nitrogen gas kept at high
pressure. When the gas cartridge is broken using the top cap the carbon dioxide under pressure
Propels the powder. The powder forms layer over the burning material to kep ar away,
Table bellow summarizes the types of fire extinguishers, indicating the chemicals they contain
andthe classes of fire the ae suitable or unsuitable fo.
Table: Types fire extinguishers and the chemical composition of heir extinguishing agents
ma
APW (Ai Ondinry ap water ‘lass B,C, and (vill pea the ame and make
pressurized ae) presi witha Clas the fe igs)
Fine sodium bierbonate Class D- Aira and eleonis cursive to meals
oder prsnuind wi | Class A, B, | such aaniionote: ‘Though iti safe owe indoor
Dy chomizalDC) nitrogen CantE ean obscure vison
Nonflammsble —cubon
dioxide gas under eteme | Class B,C Class A (eaves 4 flammable substance oo. the
co. reste and extinguished materi which cnet er)
Iromechlowdilure- Class A and
Halon methane E tas Band C(t suitable
Class A and
Foun Procisand Muow-potias 8 cust
WetchemicaWC)_Poussiumseeae CasF Cas
Clas A, | Beenie equipment (eve a icky resid that may
Monoammosim ptosate Clase B and be damaging 10 clectical appliances sich at 8
nc wit antopencanie | C compute)
Ponders of NaCl Cu or
Specialist powder graphite under extreme
6 reste Clas Class A,B,C, EandF
Precautions on using fire extinguishers
The following are some safety precautions you have 0 keep in mind when using fire
extinguisher:
m
Extinguishing Small Fires Using the Right Types of Fire Extinguishers
Rusting

The Concept of Rusting

money All ffs mist be made to tp ir ose! tems fom sting. This can be achieved if
we know te conditions necessary for iron to rst
‘The Conditions Necessary for Iron to Rust
Demonstrate the conditions necessary for iron 0 rast.
When ton sl in contact with bth water and oxygen (or i) teats to form hydrated iron
{ty oxide. hon will not rust on exposure to dy ato ai-froe water (wate that has ben boiled
to expel all disolved ir) ony. However, ron will easly and realy rust in water that has
dissolved air init In igre 68, only the ron mail that is in contact with both water and ir sts
Therefore, rusting wil only occur inte presence of both water and oxygen. If ne of the two
conditions is exchded in one way or another, sting will nt ake place tal
bet te? ies

ZZ “tA Z

“ aya
ler oe
Sey a foe St
swonite ee ais wool
ea oa iw
Findings
Nails in tube | will rst Nailin tubes 2and3 will ot ust
Reasoas
In tube 1, nails ae in contact with both water and air (oxygen, In tbe 2 the water has been
toiled to expel the dissolved sir, In addon, any ar above the water is prevented fom
cisotving in Died water by «lye of cil So, the mals are completely shicded away from i
Therefore, rstng is imposible. in tube 3, mils are in cont with ir only. The moisture
us
present in ai is absorbed by anhydrous calcium chloride. Any moisture that might have been
absorbed by the anhydrous calcium chloride is prevented from reaching the nails by a tuft of
cotton wool. The cotton woo! also absorbs some moisture directly from the air. Therefore, tube 3
will always carry dry air (moisture-fee air). Hence, no rusting of iron nails occurs.
This experiment demonstrates the fact that for ito to rust, both water and air (oxygen) must be
present. If one of these conditions is controlled, no rusting can take place
Similarity between rusting and burning
Chemically, rusting and burning are similar processes in that they both require oxygen. Consider
the burning of magnesium to give magnesium oxide.
2Mg(s) + Og) — 2MgO(s)
In this process, magnesium combines with the oxygen ofthe air to form magnesium oxide
During rusting, iron combines with oxygen of the ai inthe presence of water to form brown
hydrated iron(II) oxide, “ust”
AF e{s) + 304g) + 201.0 — 2Fe.0,.0H.0(8)
In addition, the two processes, burning and rusting, are exactly similar in that they both generate
heat. The only difference isin the time required for each of the two processes to take place.
During rusting heat is given out, but without being noticed because of its slower rate of
production. Burning produces noticeable heat and light.
‘The Different Methods of Preventing Iron from Rustin
Describe the different methods of preventing iron from rusting
We have learned that for iron to rust there must be direct contact between the iron and both water
and oxygen ffom the air. Therefore, in order to stop rusting we must protect iron from either
‘ater (moisture) or oxygen (at) or both. The following are some of the methods used to prevent
iron from rusting:
2s
Painting
1ethod is widespread for objets ranging in size fom ships and bridges to garden gates. Paints
that contain lead or zinc are mostly used. These paints ae especially good for preventing rusting
For example, red lead” paints contin an oxide of lead,
‘As onygen and water cannot reach the iron, it does not rst, However, if the pint layer is
scratched off rusting may occur So, regular repainting is necessary to keep this protection ntact.
Oiling and greasing
The oiling and/or greasing ofthe moving pars of machinery forms a protective fil, preventing
rusting, Moving parts cannot be painted since the paint layer can be easily seratched off during
‘movement. Again, the teatment must be repeated to continue the protection,
Plastic coating
Stel is coated with plastic for use in garden chairs, refrigerators, bicycle baskets, dish racks, ee
The plastic PVC (polyvinyl chloride), a trade name for polychloroethene, is often used for this
purpose. Plastic is cheap and can be made to lok atrative
Electroplating
Electroplating isthe coating of one metal with a layer of another metal by means of electrolysis
‘where the metal tobe coated isthe cathode and the coating metal he anode.
{An iron or steel objet can be electroplated with layer of chromium or tin to protect against
rusting. A ‘tin can’ is made of ste! coated on both sides with a fine layer of tin, Tin is used
because itis unreactive and non-toxic, However, if protective layer is broken, then the stel
beneath wil begin to rust. So, proper handling of tinplate items is neded.
Galvanizing
6
The zine layer can be applied by several different methods, These inclde electroplating or
dipping the object nto molten zinc. When anion or steel article i dipped into molten zine and
Sacrificial protection
zine or magnesium are attached tothe bul ofa see! ship ool ig, it comodes in preference to
the iron. When the blocks are nearly eaten away, they can be replaced by fesh blocks
Underground gas and water pipes ae connected by wire to blocks of magnesium to obtain the
meres to prevent rasting of the whole bul
a
\ JR ate
\ aN Js
\eQ__ / =
oe oe Oo

GSES EE

Blocks of zine or magnesium) atached to the hull ofa ship
Alloying
Alloys are mixtures of metals. For example, ron can be mixed with small quantities of much ess
reactive metals to form an allo called stainless steel, Stainless stot contins ion mixed with
clomium, nickel and manganese. Sunless steel does not rust. It also has a very atactive
appearance, Its used to make cutlery and kitchen equipment.
Use of silica gel
Silica is a common name for silicon dioxide (Si). Silica gel i a granular, vitreous, highly
porous form of silica made syntetcally from sodium silicate. Despite its name, silica gel i a
soli, Itis used as a desiccant, which absorbs moisture to prevent rusting of ion items or atcles.
ne

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