Chemistry Form Two Notes – Fuels and Energy

These Chemistry Form Two notes cover Fuels and Energy. The material is organised in clear sections for easier reading, understanding and revision.

Fuels And Energy

A fuel is a substance that can be combusted or burnt to release energy as a byproduct. The energy can be in the form of heat, light, electricity, sound etc. This energy can be hamessed to power machines or used for other purposes such as heating or lighting. Combustion is the burning of fuel with energy released as a byproduct. Fuel is a very important substance for the existence of a modern man. Examples of fuels include petroleum products (petrol, diesel, fuel

oil, kerosene, spirits, etc), natural gas, coal, wood, charcoal, producer gas, water gas, etc.

Fuel Sources

Different Sources of Fuels

There are many types of substances that are used as fuels. The fuels exist as solids, liquids or gases. The most common substances that are used as fuels in Tanzania include wood, wood charcoal, coal, petroleum products and natural gas. These fuels are obtained from different

sources as analysed below:

Wood: wood is obtained from logs or poles of trees. The wood used as fuel in Tanzania is obtained from natural and artificial forests. Wood fuel is mainly used in rural areas where there are no alternative fuels. Wood is also a major source of fuel used by government institutions

such as schools, colleges, hospitals, and military institutions.

Charcoal: This fuel is made by heating certain substances such as wood and bones in a limited

supply of air. Wood charcoal is the main source of fuel in urban areas and in some townships.

Coal: coal used in Tanzania is mined at Kiwira coal mines. It is used indirectly for generating electricity or directly for powering machines in processing and manufacturing industries and factories. The electricity generated from coal is used in such industries as Tanga cement and

several other industries in Dar es Salaam.

Natural gas: This gaseous fuel is mined at Songosongo in Kilwa (Lindi region), located in

southern Tanzania. The gas is used as a fuel at homes and in small industries. It is also used to

generate electricity that is used in various manufacturing and processing industries. The

electricity generated from this gas is also sold to Tanzania Electricity Supply Company

(TANESCO) who distributes the energy to its various clients.

5. Petroleum products (kerosene, diesel, petrol, fuel oil, fuel gas, etc.) These petroleum fractions are obtained from crude oil by the process of fractional distillation of crude oil (petroleum) Diesel, petrol and oil are used in vehicles and other machines. Kerosene is used in kerosene

lamps and stoves for heating at homes and for other general purposes

Methods of Obtaining Fuels from Locally Available Materials

Methods of making charcoal

When we heat certain organic matter in a limited supply of air, we obtain a black, solid residue called charcoal. The organic matter can be from plant or animal sources for example, wood or

animal bones. Heating a substance in limited supply of air is called destructive distillation

Wood or bone charcoal is made by the process of destructive distillation of wood or bones respectively. Charcoal is largely pure carbon. The entry of air during carbonization (destructive distillation) process is controlled so that the organic material does not burn down to ash as in

conventional fire, but instead decompose to form charcoal Procedure for making wood charcoal

Cut wood into small pieces.

Arrange the wood pieces into a pile of wood on the ground.

Cover the pieces of wood with soil, leaving one open space for setting fire. Set fire to the wood and then cover the open space with soil. Make sure that the wood is burning.

After the wood is burned, uncover the soil and pull out the black solid substance underneath.

This is the charcoal. Coal formation

Coal is formed from the remains of lush vegetation that once grew in warm shallow coastal

swamps. The following are the stages in the process of coal formation:

The dead vegetation collects in the bottom of the swamp. It may start to decay. But decay soon stops, because the microbes that cause it need oxygen, and the oxygen dissolved in the stagnant,

warm water is quickly depleted The vegetation is buried under debris,

Over hundreds of thousands of years, the environment changes. Seas flood the swamps. Heavy layers of sediment pile up on the dead vegetation, squeezing out gas and water and tuming it

into peat

As the peat is buried deeper, the increasing heat and pressure compress it progressively to form

different types of coal

As the process continues, the coal s harder and more compact. Its carbon content also increases, giving different types of coal. Table bellow shows a summary of the stages in the process

Name of coal Carbon content

Peat 60%

Pressure and Heat Lignite % Hardness

Bituminous coal 80'

Anthracite 95°

As carbon content increases so does energy given out per unit weight. But hard coal tends to

have higher sulphur content,hence likely to cause environmental pollution. When burnt, the sulphur in the coal produces sulphur dioxide gas that is released into the atmosphere, causing air

pollution. S,.;+O2)->St

Categories of Fuels Fuels can be classified into three groups according to the physical state of the fuel. A fuel can be

in any of the three states of matter namely, solid, liquid or gaseous state.

Fuels According to their States

Solid fuels

Solid fuels include wood, charcoal, peat, lignite, coal, coke, etc. The immediate use of all these fuels is for heating and lighting. However, these fuels have a long history of industrial use. Coal was the fuel for the industrial revolution, from firing furnaces to running steam locomotives and trains. Wood was extensively used to run locomotives. Coal is still used for generation of power until now. For example, in Tanzania the coal mined at Kiwira is used for generation of electricity. Also Tanga Cement Company uses coal as a source of power to run machines for

production of cement.

Wood is used as a solid fuel for cooking, heating or, occasionally, as a source of power in steam engines. The use of wood as a fuel source for home heating is as old as civilization itself. Wood

fuel is still common throughout much of the world. It is the main source of energy in rural areas.

Wood charcoal yields a large amount of heat in proportion to its quantity than is obtained from a corresponding quantity of wood, and has a further advantage of being smokeless. Wood charcoal

is often used for cooking and heating, in blacksmithing, ete

Animal charcoal is used for sugar refining, water purification, purification of factory air and for

removing colouring matter from solutions and from brown sugar. Animal charcoal is made by

destructive distillation of animal bones.

Coke is a fuel of great industrial use. Coke is obtained by destructive distillation of coal. Most of the coke produced in industry is used as a reducing agent in the production of metals such as pig iron. A substantial amount of coke is also used for making industrial gases such as water gas and

producer gas.

Coke is a better fuel than coal because when it is burning, it produces a clean and smokeless flame. When coal is used as a fuel, it produces many toxic gases during burning. Coke has high

heat content and leaves very little ash.

Coal is a complex mixture of substances, and its composition varies from one place to another. It depends on coal’s age and condition under which it was formed. Anthracite is a very hard black

coal and it is the oldest of all types of coal.

When coal is heated in a limited supply of air, it decomposes. This thermal decomposition is called destructive distillation of coal. The products are coke, coal tar, ammoniacal liquor and

coal gas Liquid fuels

Liquid fuels include petrol (gasoline) diesel, alcohol (spirit), kerosene (paraffin), liquid hydrogen, etc. Liquid fuels have advantage over solid fuels because they produce no solid ashes, and can be regulated by automatic devices. They are relatively more convenient to handle, store

and transport than solid fuels.

Most liquid fuels in wide use are derived from fossils. Fossil fuels include coal, natural gas and petroleum. These fuels are formed from remains of sea plants and animals which lived millions of years ago. The remains became buried under layers of sediment. Immense heat and pressure

resulted in the formation of coal gas and oil

Energy produced when petroleum products (diesel, petrol, kerosene, natural gas etc) are burned, originated from the sun. This energy was transferred to animals through their consumption of plants or plant products. When the animals died, got buried, and compressed by heat and

pressure, they produced oil which gives off that energy when burnt

Petroleum fuels are used in cars and in various other machines. Fuels used in cars and lories

(petrol and diesel), kerosene (for jet aircraft) and fuel oil (for ships), all came from crude oil

Some oil fuel is also used for electricity generation.

Ethanol burns with a clean, non-smoky flame, giving out quite a lot of heat. On a small scale, ethanol can be used as methylated spirit (ethanol mixed with methanol or other compounds) in spirit lamps and stoves. However, ethanol is such a useful fuel that some countries have developed it as a fuel for cars. In countries where ethanol can be produced cheaply, cars have

been adapted to use a mixture of petrol and ethanol as fuel.

Brazil has a climate suitable for growing sugarcane. Ethanol produced by fermentation of sugarcane has been used as an alternative fuel to gasoline (petrol), or mixed with gasoline to produce "gasohol”. Currently, about half of Brazil’s cars run on ethanol or "gasohol". "Gasohol"

now accounts for 10% of the gasoline sales in the U.S.A.

The idea about the use of biofuel for fuelling automobiles and other machines has been borrowed by other countries including Tanzania. However, the programme has raised a bitter concern among different activists. Their doubt is that emphasis on growing crops for biofuel production may take up land that could otherwise be used for growing food crops. This, therefore, would mean that there would not be enough land to grow enough food to feed the ever-increasing human population. Hence, hunger will prevail. Notwithstanding all these shouting, biofuel crop

production is there to stay! Gaseous fuels

The use of gaseous fuels for domestic heating is common in urban areas. Compressed gas that is delivered to our homes in steel cylinders is liquefied propane, butane, or mixture of the two.

When the valve is opened, the liquid gas vaporizes quickly into gas and passes through a pipe to

the stove. Gaseous fuels are the most convenient fuels to handle, transport and store.

The following is a list of types of gaseous fuels:

Fuel naturally found in nature: -natural gas -methane from coal mine

Fuel gas from solid fuels or materials: -gas derived from coal (water gas and producer gas) –

derived from wastes and biomass (biogas)

Fuel gas made from petroleum

Gaseous fuels used in industry

Producer gas and water gas are important industrial fuels. Producer gas

Producer gas is produced by burning a solid carbonaceous fuel, such as coke, in a limited supply

of air in a producer furnace. The reaction is exothermic and this makes coke to get hotter.

Carbonaceous fuels are fuels that contain a high proportion of carbon. The producer gas is a

mixture of carbon monoxide and nitrogen.

When air, mixed with a little steam, is passed through the inlet in the lower part of the furnace, the coke (carbon) combines with oxygen (from air) to form carbon dioxide

Gy + Ox. > CO, AH = —406 kJ mol

As the carbon dioxide formed rises up through the red-hot coke, it is reduced to carbon

monoxide:

COy,, +C, 92C0,, ‘AH =+163 kJ mol"

Since more heat (406 kJ) is produced in the lower part than is absorbed in the upper part of the

furnace (163 kJ), some excess heat is obtained in the long run. This heat keeps the coke hot. The

nitrogen gas in the air is not affected at all during the process. Hence, the overall reaction

equation may be represented as follows:

Producer gas

As a fuel, producer gas bums to give out carbon dioxide.

2CO,,, + Ox, > 2CO»,

Because a good deal of producer gas contains nitrogen, a gas that does not support combustion, it

has a lower calorific value compared to water gas. See table 4.2 for comparison.

Water gas

Water gas is produced by passing steam over white-hot coke at 1000°C. The gas is a mixture of

hydrogen and carbon monoxide. The reaction is endothermic, causing the coke to cool

HO. +C.y 9 CO. +Hy. “AH=117kJ mol

Water gas burns as a fuel to give carbon dioxide and steam

CO. + Hy) + Os, > COs, +H30,,

ew)

Water gas

However, carbon monoxide is a very poisonous gas. The gas made from petroleum or coal contains some carbon monoxide, which makes it poisonous. Natural gas is safer and efficient, as

it contains no carbon monoxide.

Characteristics of a good fuel

A good fuel burns easily to produce a large amount of energy. Fuels differ greatly in quality.

There are certain characteristics, which make a good fuel. After all, there is no fuel among the different fuels known that posses all the virtues that a good fuel should have. Generally, a good

fuel has the following charact It should be environmentally friendly (not harm the environment) in the course of its production

and use, that is, it should not produce harmful or toxic products such as much smoke, carbon

dioxide, carbon monoxide, sulphur dioxides, etc, which pollutes the air It must be affordable to most people i.e. it must be cheap It should not emit or produce dangerous by-products such as poisonous fumes, vapour or gas

It should have high calorific value i.e. it must burn easily and produce a tremendous quantity of

heat energy per unit mass of the fuel

It should be easy and safe to transport, store, handle and use.

Si

It should be readily available in large quantities and easily accessible

It should have high pyrometric burning effect (highest temperature that can be reached by a burning fuel). Normally gaseous fuels have the highest pyrometric effect as compared to liquid

and solid fuels.

It should have a moderate velocity of combustion (the rate at which it burns) to ensure a steady

and continuous supply of heat.

A good fuel should have an average ignition point (temperature to which the fuel must be heated before it starts burning). A low ignition point is not good because it makes the fuel catch fire

easily, which is hazardous, while high ignition point makes it difficult to start a fire with the fuel

A good fuel should have a low content of non-combustible material, which is left as ash or soot when the fuel burns. A high content of no-combustible material tends to lower the heat value of

the fuel.

Calorific values of fuels

The heating value or calorific value of a substance, usual fuel or food, is the amount of heat released during the combustion of a specific amount of it. The calorific value is a characteristic

of each substance. It is measured in units of energy per unit of substance, usually mass, such as

Keal/Kg, J/g, KJ/Kg, KJ/Mol, MJ/m’, etc. Heating value is commonly determined by use of an

instrument called bomb calorimeter.

By custom, the basic calorific value for solid and liquid fuels is the gross calorific value at

constant volume, and for gaseous fuels, it is the gross calorific value at constant pressure

Solid and liquid fuels Calorific value (MJ/kg) Alcohols

Ethanol

Methanol

Coal and coal products

Anthracite (4% water)

Coal tar fuels

General purpose coal (5-10% water)

High volatile coking coals (4% water)

Low temperature coke (15% water)

Medium-volatile coking coal (1% water)

Steam coal (1% water)

Peat

Peat (20% water)

Petroleum and petroleum products

Diesel fuel

Gas oil

Heavy fuel oil

Kerosene

Light distillate

Light fuel oil

Medium fuel oil 43

Petrol 44.80 – 46.9

Wood

Wood (15% water) 16

Gaseous fuels at 15°C, 101.325 kPa, dry Calorific value (MJ/m*)

Coal gas coke oven (debenzolized) 20

Coal gas low temperature 34

Commercial butane

Commercial propane

North sea gas, natural

Producer gas coal

Producer gas coke

Water gas carbureted

Water gas blue Measuring the heat given out by fuels

We burn fuels to provide us with heat energy. The more heat a fuel gives out the better. The amount of heat given out when one mole of fuel burns is called heat of combustion. This is often

written as

A Heceesion

This value can be measured in the laboratory indirectly by burning the fuel to heat water. Simple

apparatus is shown in figure bellow. The basic idea is: Heat gained by the Heat gained by the water = heat given out by the fuel

Method

These are the steps

Pour a measured volume of water into the tin. Since you know its volume you also know its mass

(1 cm! of water has a mass of 1g)

Weigh the fuel and its container.

Measure the temperature of the water.

Light the fuel and let it burn for a few minutes.

Measure the water temperature again, to find the increase.

Reweigh the fuel and container to find how much fuel was burned.

thermometer

— clamp

}-— 100g water

spirit lamp =——

Calculations

It takes 4.2J of energy to raise the temperature of 1g of water by 1°C. This constant value is

called specific heat capacity of water, usually represented as 4.2J,'C"' (4.2 joules per gram per

centigrade). So, you can calculate the energy given out when the fuel burns by using this

equation Energy given out = 4.2,.:C’' mass of water (g) its rise in temperature (°C).

Then since you know what mass of fuel you burned you can work out the energy that would be

given out by buming one mole of it

The experiment gave these results for ethanol and butane. Make sure you understand the calculations:

Ethanol (burned in a spirit lamp) Butane (bumed in a butane cigarette lighter) Results Results

Mass of ethanol used: 0.9 Mass of butane: 0.32g¢

Mass of water used: 200g Mass of water used: 200g

Temperature rise: 20°C Temperature rise: 12°C

Calculations Calculations

Heat given out = or 16.8KJ Heat given out 10080J or10.08KJ

The formula mass of ethanol is 46. 0.9g gives The formula mass of butane is 58. 0.32 gives out out 16.8KJ of energy. So, 46g gives out of 10.08KJ of energy. So, 58g gives out KJ of

energy energy

So, H combustion for ethanol is -859KJ/mol So, H combustion for butane is -1827 KJ/mol

Determination of energy (calorific) value of ethanol The energy/heating/calorific value of a fuel refers to the amount of heat given out when a

specific amount of fuel is burned.

Experiment

Aim: To find out the energy value of ethanol

Materials: water, beaker, thermometer, weighing balance, spirit lamp and ethanol. Procedure:

Pour a known volume of water into a beaker.

Measure the temperature of the water.

Fill the spirit lamp with enough ethanol.

Weight the mass of both the ethanol and the lamp.

Light the lamp and let it continue burning for a few minutes before putting it off. Measure the water temperature again, to find the increase.

Reweigh the ethanol and its container to find how much ethanol was burned. Record the following:

Mass of spirit lamp + ethanol (initially)

Mass of spirit lamp + ethanol (finally)

Mass of ethanol burned

Final temperature of water

Initial temperature of water Rise in temperature of water

Mass of water

The amount of heat (q) released by ethanol is given by

q=MC@, where

q = quantity (amount) of heat released

M= mass of water

C = specific heat capacity of water

• @ = rise in temperature (final temperature—initial temperature)
• Specimen calculation:
• Mass of lamp and ethanol initially = 50g
• Mass of lamp and ethanol finally = 49.5g
• Mass of ethanol burned = 50.0 — 49.5 = 0.5g¢
• Mass of water = 100g
• Final temperature of water = 42°C

Initial temperature of water = 20°C

Rise in temperature = 42°C — 20°C = 22°C

Specific heat capacity of water = 4.2 Jg'C'

Heat given out = Mass of water Xspecific heat capacity Xtemperature rise

.". Heat obtained by burning 0.5g of ethanol = 9.24KJ. One mole of ethanol C,H ,OH) =(2×12+1×5+16+1) = 46g, If

0.5g of ethanol gives out 9.24KJ of energy, 46g gives out

40 59,24 = -850KJ / mol OS

Repeat similar procedures with kerosene, charcoal, coal, firewood etc. and compare your results

Which fuel has more energy per gram? That is the most efficient fuel

the experiment?

The following table compares the experimental results with values from data book.

Fuel Heat of combustion in KJ/mol From the experiment From a data book Ethanol -859 -1367

Butane -1827 -2877

Note the big difference! The experimental results are almost 40% lower for both fuels. Why do

you think there is such a big difference? There are two reasons for this:

Heat loss: Not all the heat from the burning fuel is transferred to the water. Some is lost to the

air, and some to the container that holds the fuel

Incomplete combustion: In case of a complete combustion, all the carbon in a fuel is converted

to carbon dioxide. But here combustion is incomplete. Some carbon is deposited as soot on the bottom of the lamp and some converted to carbon monoxide. For example, when butane burns, a

mixture of all these reactions may take place

2C Hy») +130, 28CO,,, +101,0,,

Carbon dioxide

2C,H po) ») + 90x.) 4 8CO,, + 10H 20.

Carbon monoxide

2C, Hyp) +50s,y) 28C,, +1017,0,, Carbon

The less oxygen there is, the more carbon monoxide and carbon will form.

Uses of Fuels

You have already learned different types of fuels and their energy values. Fuels can be put into several uses. The use of a given kind of a fuel for a particular function depends on the economic

value of that use. Generally, the uses of fuels include the following:

1. Source of mechanical power: Vehicles, machines and several other devices are powered by fuels such as diesel, petrol, oil, ete as a source of mechanical power. In some countries, vehicles have been modified to use natural gas as a source of power. In Tanzania for example, plans are underway to modify car fuel systems so that a natural gas obtained from Songosongo in Kilwa could power cars. This will help a great deal to reduce the cost of running cars on liquid fuels whose price in the world market is continuously escalating. Hydrogen may become an important

fuel for cars and homes in the future, as we run out of oil and gas. It has two big advantages: Its reaction with oxygen produces just water. No pollution to the environment!

It is a ‘renewable’ resource. It can be made by electrolysis of acidified water. As cheaper sources

of electricity for electrolysis are developed, this may become an attractive option.

2. Cooking and heating: Fuels like wood, liquefied gas (propane or butane or a mixture of the two), charcoal and kerosene are burned to provide energy for cooking and heating. When burned, these substances provide enough heat to cook food and even heat different substance at home. Inhabitants of cold countries in temperate regions of the world burn different kinds of fuels to

produce heat for heating homes and water.

3. Generation of electricity: The machines and devices responsible for electricity production and supply are fuelled by heavy liquid fuels such as diesel, fuel oil, etc. Most generators use liquid fuels such as petrol and diesel to generate electricity. So, fuels play an important role in electricity production. In Tanzania, coal from Kiwira mines is used for generation of electricity used in Tanga Cement Factory and some industries in Dar es Salaam. This is why escalation of crude oil in the world market results to increased cost of electricity supplied to homes and industries. In developed countries, uranium is used as a fuel to generate electricity which is used

at homes and in industries.

4. Lighting: Kerosene is used in paraffin lamps, tin lamps and hurricane lamps by the rural

communities to light homes. The use of paraffin is important in rural areas of Tanzania where 90% of the total population stay and earn their living. It is estimated that only 10% of the population have access to electricity. So, you can see how crucial this fuel is to the majority of

the people.

5. Industrial uses: Industrial operations such as welding and metal fabrication make use of

oxyacetylene flame which produces extremely high heat to melt and cut metals.

6. Other alternative uses: manufacture of different kinds of products such as petroleum jelly,

nylon and plastic.

The Environmental Effects on Using Charcoal and Firewood as Source of Fuels Trees are the most common source of fuels in developing countries like Tanzania. Fuels from trees are mainly used for domestic purposes. People cut down trees for firewood and for burning

charcoal that is mainly supplied to urban areas to be used as fuel

Because of the rapidly growing human population, the demand for trees as a source of fuel has ever increased to the extent that this resource is no longer sustainable. The act of cutting down trees for firewood, charcoal, timber, and for obtaining logs that are shipped to overseas has made this resource to be depleted. This leads to environmental destruction, a result that causes many

problems to the human society and other organisms as well.

Trees have several advantages apart from providing us with fuels. Trees help in the attraction of rainfall and conservation of water sources in various areas. Trees also help in removing bad

gases from air such as carbon dioxide that is emitted to the atmosphere due to various human

activities. In so doing, trees help to maintain the balance of gases in the atmosphere.

Trees and other vegetation provide habitats and shelters for wild animals and birds of the air. Presence of trees also help to maintain the survival of microorganisms found in the soil, which are important for the balance of nature. Trees can make our country look beautiful and hence attract local and foreign eco-tourists, a fact which can contribute to our country’s revenue, and

economic growth.

Deforestation results to scarcity of rainfall as we are experiencing these years. This trees attract rainfall. Scarce rainfall leads to drought. Prolonged drought causes famine Therefore, people will suffer from famine if they continue to use firewood or charcoal as their

sources of fuels.

The other effect is soil erosion, which leads to loss of soil fertility. Trees act as a soil cover,

which makes the soil resist the impact of raindrops. Deforestation means removal of the soil

cover and hence making the soil bare. It is obvious that tree cutting for firewood or charcoal will expose the soil to agents of soil erosion such as wind, water and animals. This will make the soil more prone to erosion. So long as plants depend on the top soil (which contains more plant nutrients) for survival and existence, an eroded soil will consequently support very few or no

vegetation at all. The aftermath of this is soil aridity.

As noted early, trees help absorb excess carbon dioxide produced by respiring living organisms. Cutting down trees will lead to excessive accumulation of carbon dioxide in air. Carbon dioxide, among other gases, is responsible for excessive heating of the earth, a phenomenon called global warming. This is because the gas forms a layer in the atmosphere that acts as a blanket. The layer

of carbon dioxide gas so formed prevents heat emitted by the heated earth from escaping to the

upper atmosphere. This causes extreme heating of the earth’s surface. Consequences of global

warming are many, the worst being drought that could ultimately lead to extinction of plant and

animal sp

Vegetation that has dried up due to prolonged drought

In brief, cutting down trees for charcoal and firewood can lead to the following environmental

problems: prolonged drought spells and hence famine: drastic change in rainfall patterns;

global warming and climate change;

increased soil erosion and rapid depletion of soil nutrients; increased aridity and desertification;

loss of valuable species of economic or medicinal value; broken food chain and reduced ecosystem stability; destruction of animal habitats and shelters;

extinction of animal, microbial and plant species; and

loss of biodiversity

Therefore, it is important to plant more trees and to reduce our dependence on trees for fuels in order to improve our environment. Tree planting campaign should be a regular practice and the trees that have already been planted should be cared for. Natural forests should be conserved. Local Governments should be encouraged to make and enforce the bylaws against those people cutting down trees carelessly for charcoal burning. At the same time, the central Government

must look for the alternative energy sources for her citizens urgently.

Continued use of trees for fuels will end up our life on earth. Let us take actions to conserve our

environment so that we continue living a healthy life.

Conservation of Energy

What is energy?

Energy is defined as the ability to do work or bring about change. Energy makes changes; it does things for us. It moves cars along the road, and boats over the water. It bakes cakes in the oven and keeps ice frozen in the freezer. It plays our favourite songs on the radio and lights our homes. Energy makes our bodies grow and allow our minds to think. People have learned how to change energy from one form to another so that we can do work more easily and live more

comfortably. The source of all energy on earth is the sun

Forms of energy

Energy exists in many different forms such as heat, light, sound, electrical, etc. The amount of

energy can be measured in joules, kilojoules, megajoules, calories, etc. There are many forms of

energy, but they can all be put in two categories: Kinetic and Potential.

Kinetic Energy

Kinetic energy is energy in motion of waves,

electrons, atoms, molecules, substances, and objects.

• Electrical energyis the movement of electrical
• charges. Everything is made of tiny particles called
• atoms. Atoms are made of even smaller particles
• called electrons, protons and neutrons. Applying a
• force can make some of the electrons move. Electrical
• charges moving through a wire is called electricity.

Lightning is another example of electrical energy.

• Radiant energy is electromagnetic energy that travels
• in transverse waves. Radiant energy includes visible
• light, x-rays, gamma rays and radio waves. Light is
• one type of radiant energy. Solar energy is an example

of radiant energy.

Thermal energy, or heat energy, is the internal energy in substances caused by the vibration and movement

of the atoms and molecules within substances.

Geothermal energy is an example of thermal energy.

Potential Energy

Potential energy is stored energy and the energy

of position – gravitational energy.

• Chemical energy is energy stored in the bonds of
• atoms and molecules. This energy holds these
• particles together. Biomass, petroleum, natural gas,
• and propane are examples of stored chemical

energy.

Stored mechanical energy is energy stored in objects by the application of a force. Compressed springs and stretched rubber bands are examples of

mechanical energy.

• Nuclear energy is energy stored in the nucleus of
• an atom – the energy that holds the nucleus
• together. The energy can be released when the
• nuclei are combined or when a nucleus splits apart
• (disintegrates). Nuclear power plants split the
• nuclei of uranium atoms in a process called fission.

The sun combines the nuclei of hydrogen atoms in

• Motion energy is the energy which enables movement
• of objects and substances from one place to another.
• Objects and substances move when a force is applied
• according to Newton's laws of motion. Wind is an

example of motion energy.

• Sound energy is the movement of energy through
• substances in longitudinal (compression/rarefaction)
• waves. Sound is produced when a force causes an
• object or substance to vibrate – the energy is

transferred through the substance in a wave

a process called fusion. Scientists are working creating fusion energy on earth, so that someday

there might be fusion power plants.

• Gravitational energy is the energy of position or
• place. A rock resting at the top of a hill contains
• gravitational potential energy. Hydropower, such
• as water in reservoir behind a dam, is an example

of gravitational potential energy.

Kinetic energy is energy in motion. Its existence can be shown by winds, ocean currents, running

water, moving machines or a falling body

Potential energy is energy at rest. It is found stored in different forms, e.g. in coal, petroleum and

natural gas, batteries and mt

s. Such energy does not work so long as it is stored. It is capable

of doing work when it is converted to other forms of energy such as heat, light or radiation

The Law of Conservation of Energy

Energy conversion (Energy changes)

Can energy be created or destroyed? When wood or charcoal is burned, it appears as if energy is

destroyed and wasted. In fact, the energy in these kinds of fuels is not destroyed when the fuels

are bumed. It is simply converted to other forms of energy such as heat and light.

When you are seated on a desk in class, you are possessing potential energy. When you stand up and walk away from the classroom, you are transforming the potential (chemical) energy in your

muscles to kinetic energy.

The Law of Conservation of Energy states that energy can neither be created nor destroyed but

it can only be changed from one form to another. When we use energy, it does not disappear. We

simply convert it from one form to another.

Potential (chemical) energy in a dry cell is converted to electrical energy which is finally converted to sound energy in radio speakers. In a tape record player, the same chemical energy is ultimately converted to kinetic energy to e the cassettes. When the potential energy is all used up, the batteries are dead. In the case of rechargeable batteries, their potential energy is

restored through recharging

The chemical energy in your mobile phone battery can be converted into sound, light, text, etc

The main energy changes that occur in a variety of simple situations are: Battery chemical to electrical, sound or light;

Car engine chemical to mechanical and then kinetic;

Light bulb electrical to light and heat;

Parachutist potential to kinetic;

Solar heat to electrical and kinetic;

Wind mill kinetic to electrical;

Running water kinetic to electrical;

Muscles chemical to kinetic, ete.

What other situations of energy changes do you know? Mention them

Alll energy changes that occur during chemical and physical changes must conform to the Law of Conservation of Energy, that is, energy can only be changed from one form into its equivalent of

another form with no total loss or gain.

The most common form of energy in chemistry is the heat change. A chemical reaction must involve some change in energy. As the reaction occurs, chemical bonds of reactant molecules are broken while those of the product molecules are formed. Energy is given out when a chemical

bond forms and it is consumed when a bond is broken.

Take an example of combustion (respiration) of glucose in living cells:

C,H,,0, + 60, > 6Co,+6H,O Ah =

During respiration process, the bonds of glucose and oxygen are broken down while those of carbon dioxide and water are formed. Heat is absorbed when chemical bonds are broken and it is released when the bonds are formed. The total amount of heat absorbed by the reactants is equal that released by the products. Heat absorbed is given a positive sign (+ve) while heat given out is assigned a negative sign (-ve). So the total energy change is equal to zero. This means that no

energy has been created or destroyed.

Experiments on the Conservation of Energy from One Form to Another

Carry out experiments on the conservation of energy from one form to another

Carry out experiments on the conservation of energy from one form to another

Renewable Energy Biogas

Renewable energy sources include biomass, geothermal energy, hydroelectric power, solar energy, wind energy, and chemical energy from wood and charcoal. These are called renewable energy sources because they are replenished within a short time. Day after day, the sun shines, wind blows, river flows and trees are planted. We use renewable energy sources mainly to

generate electricity.

In Tanzania most of the energy comes from non-renewable sources. Coal, petroleum, natural gas,

propane and uranium are examples of non-renewable energy sources. These fuels are used to

generate electricity, heat our homes, move our cars and manufacture many kinds of products.

These resources are called non-renewable because they cannot be replenished within a short

time. They run out eventually. Once, for example, coal or petroleum is depleted, it may take

millions of years to be replaced. So, these are non-renewable energy sources BIOGAS

Biogas is a gaseous fuel produced by the decomposition of organic matter (biomass). Under anaerobic conditions, bacteria feed on waste organic products, such as animal manure and straw, and make them decay. The product formed from this decay is called biogas, which consists mainly of methane, though other gases such as carbon dioxide, ammonia, etc, may also be produced in very small quantities. The biogas produced can be used as a fuel for cooking,

heating, etc.

Raw materials for biogas production may be obtained from a variety of sources, which include livestock and poultry wastes, crop residues, food processing and paper wastes, and materials

such as aquatic weeds, water hyacinth, filamentous algae, and seaweeds.

‘The Working Mechanism of Biogas Plant

Explain the working mechanism of biogas plant

The organic waste products are fed in a biogas plant. Prior to feeding the material into the plant, the raw material (domestic poultry wastes and manure) to water ratio should be adjusted to 1:1

ie. 100 kg of excreta to 100 kg of water. Then adequate population of both the acid-forming and

methanogenic bacteria are added.

The bacteria anaerobically feed on the liquid slurry in the digester. The major product of this microbial decomposition is biogas, which largely contain methane gas. The gas so produced is collected in the gas holder and then taped off. The gas is used as a fuel for cooking, heating and

other general purposes. The biological and chemical conditions necessary for biogas production

Domestic sewage and animal and poultry wastes are examples of the nitrogen-rich materials that provide nutrients for the growth and multiplication of the anaerobic organisms. On the other hand, nitrogen-poor materials like green grass, maize stovers, etc are rich in carbohydrates that

are essential for gas production. However, excess availability of nitrogen leads to the formation

of ammonia gas, the concentration of which inhibits further microbial growth. This can be

corrected by dilution or adding just enough of the nitrogen-rich materials at the beginning.

In practice it is important to maintain, by weight, a C:N close to 30:1 for achieving an optimum rate of digestion. The C:N can be manipulated by combining materials low in carbon with those

that are high in nitrogen, and vice versa.

A pH range for substantial anaerobic digestion is 6.0 — 8.0. Efficient digestion occurs at a pH

near to neutral (pH 7.0). Low pH may be corrected by dilution or by addition of lime.

To ensure maximum digestion, stirring of the fermentation material is necessary. Agitation (stirring) can be done either mechanically with a plunger or by means of rotational spraying of fresh organic wastes. Agitation ensures exposure of new surfaces to bacterial action. It also promotes uniform dispersion of the organic materials throughout the fermentation liquor, thereby

accelerating digestion. A Model of Biogas Plant The biogas plant consists of two components: the digester (or fermentation tank) and a gas

holder. The digester is a cube-shaped or cylindrical waterproof container with an inlet into which

the fermentable mixture is introduced in the form of liquid slurry. The gas holder is normally an

airproof steel container that floats on the fermentation mix. By floating like a ball on the

fermentation mix, the gas holder cuts off air to the digester (anaerobiosis) and collects the gas generated. As a safety measure, it is common to bury the digester in the ground or to use a green

house covering.

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Structure of the biogas plant

The Use of Biogas in Environmental Conservation

Environmental conservation is a major concern in life. We need to live in a clean and health environment so as to enjoy our lives better. The use of biogas as an alternative source of energy is essential in environmental conservation due to a number of reasons. These are some of the

reasons:

Biogas does not produce much smoke or ash, which could otherwise pollute the atmosphere or land. When the gas is bumed it produces very little smoke and no ash as compared to other

sources of fuel such as wood.

The use of biogas for cooking and heating prevents the cutting down of trees to harvest firewood,

or bum charcoal for fuel, a practice that could result to soil erosion, drought, etc. Hence, using

the biogas as fuel helps to conserve the environment as no more cutting of trees may be done.

Using cow dung, poultry manure and other excreta for biogas production helps keep the environment clean because these materials are put into alternative use instead of just being

dumped on land, a fact that could lead to pollution of the environment

Some biomass employed in biogas production is toxic and harmful. By letting these materials be digested by bacteria, they may be turned into non-toxic materials that are harmless to humans,

plants, animals and soil

The excreta used for production of biogas produce foul smell if not properly disposed of. Using

this excrete to generate biogas means no more bad smell in air. Health hazards are associated with the use of sludge from untreated human excreta as fertilizer. In general, a digestion time of 14 days at 35°C is effective in killing the enteric bacterial

pathogens and the enteric group of viruses. In this context, therefore, biogas production would

provide a public health benefit beyond that of any other treatment in managing the rural health

and environment of developing countries.